Decomposition of hydrazine complexes of cadmium sulfate

A series of complexes of cadmium sulfate with hydrazine has been synthesized and the decomposition reactions of the complexes have been studied using TG and DSC. Some of the complexes were found to lose hydrazine at ambient temperature. In general, several of the complexes appear to be nonstoichiome...

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Bibliographic Details
Published in:Thermochimica acta 1989-09, Vol.150 (1), p.79-86
Main Authors: House, J.E., Vandenbrook, A.J.
Format: Article
Language:English
Subjects:
Chemistry
Exact sciences and technology
Inorganic chemistry and origins of life
Kinetics and mechanism of reactions
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Summary:A series of complexes of cadmium sulfate with hydrazine has been synthesized and the decomposition reactions of the complexes have been studied using TG and DSC. Some of the complexes were found to lose hydrazine at ambient temperature. In general, several of the complexes appear to be nonstoichiometric, with hydrazine to CdSO 4 ratios in the range of 1.05 to 2. Kinetic parameters and Δ H values are presented for some of the reactions, but others were found to be too indistinct to permit reliable analysis of the TG data.
ISSN:0040-6031
1872-762X
DOI:10.1016/0040-6031(89)85313-4