Thermal studies on some lanthanide(III) complexes of hexamethylenedithiocarbamate

Hexamethylenedithiocarbamate complexes of lanthanides of the type Ln(C 6H 12NCS 2) 3 (where Ln ≡ La, Pr, Nd, Sm, Tb and Dy) were synthesized. Spectral studies (IR and UV) indicate that the hexamethylenedithiocarbamate moiety is bidentate. Thermogravimetric studies reveal that the complexes undergo v...

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Bibliographic Details
Published in:Thermochimica acta 1989-03, Vol.141, p.69-75
Main Authors: Dahiya, Krishan Kumar, Kaushik, Narender Kumar
Format: Article
Language:English
Subjects:
Chemistry
Exact sciences and technology
Inorganic chemistry and origins of life
Kinetics and mechanism of reactions
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Summary:Hexamethylenedithiocarbamate complexes of lanthanides of the type Ln(C 6H 12NCS 2) 3 (where Ln ≡ La, Pr, Nd, Sm, Tb and Dy) were synthesized. Spectral studies (IR and UV) indicate that the hexamethylenedithiocarbamate moiety is bidentate. Thermogravimetric studies reveal that the complexes undergo volatilization without decomposing. The heats of vaporization were calculated from the differential thermal analysis curves.
ISSN:0040-6031
1872-762X
DOI:10.1016/0040-6031(89)87042-X