Excess enthalpies of 1-octanol with cyclohexane at 298.15 K

Heats of mixing at high dilutions were determined for the binary system 1-octanol + cyclohexane at 298.15 K. The standard molar enthalpy of H-bond formation of 1-octanol was evaluated. The values measured for 1-octanol + cyclohexane, and for other n-alcohol+ cyclohexane systems, were correlated by p...

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Bibliographic Details
Published in:Thermochimica acta 1990-12, Vol.173, p.273-279
Main Authors: Domanska, Urszula, Domański, Krzysztof, Klofutar, Cveto, Paljk, Špela
Format: Article
Language:English
Subjects:
Chemical thermodynamics
Chemistry
Exact sciences and technology
General and physical chemistry
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Summary:Heats of mixing at high dilutions were determined for the binary system 1-octanol + cyclohexane at 298.15 K. The standard molar enthalpy of H-bond formation of 1-octanol was evaluated. The values measured for 1-octanol + cyclohexane, and for other n-alcohol+ cyclohexane systems, were correlated by polynomials and with the UNIQUAC associated- solution model.
ISSN:0040-6031
1872-762X
DOI:10.1016/0040-6031(90)80613-4