A DSC study of the phase transition in potassium thiocyanate

The phase transition that occurs at 413 K in potassium thiocyanate has been studied using differential scanning calorimetry. The transition was found to be reversible and the apparent Δ H value is dependent on heating/cooling rate. The transition displays a thermal hysteresis that also depends on ra...

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Bibliographic Details
Published in:Thermochimica acta 1992-09, Vol.206, p.91-94
Main Authors: Hamilton, C.D., House, J.E.
Format: Article
Language:English
Subjects:
Chemical thermodynamics
Chemistry
Elements, mineral and organic compounds
Exact sciences and technology
General and physical chemistry
Thermodynamic properties
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Summary:The phase transition that occurs at 413 K in potassium thiocyanate has been studied using differential scanning calorimetry. The transition was found to be reversible and the apparent Δ H value is dependent on heating/cooling rate. The transition displays a thermal hysteresis that also depends on rate of heating and cooling.
ISSN:0040-6031
1872-762X
DOI:10.1016/0040-6031(92)85287-6