Energy transfer in irradiated cyclohexane solutions

From the decrease of yield of solvent fluorescent excited states in cyclohexane by the electron scavenger CO 2 the efficiency of formation of this excited state from ion recombination is found to be 0.4 ± 0.1. Energy transfer studies using cis-decalin as a solute seem to provide evidence for the for...

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Bibliographic Details
Published in:Radiation physics and chemistry 1985, Vol.26 (5), p.509-511
Main Authors: Luthjens, L.H., de Leng, H.C., Wojna´rovits, L., Hummel, A.
Format: Article
Language:English
Subjects:
Chemistry
Exact sciences and technology
General and physical chemistry
Physical chemistry of induced reactions (with radiations, particles and ultrasonics)
Radiation chemistry
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Summary:From the decrease of yield of solvent fluorescent excited states in cyclohexane by the electron scavenger CO 2 the efficiency of formation of this excited state from ion recombination is found to be 0.4 ± 0.1. Energy transfer studies using cis-decalin as a solute seem to provide evidence for the formation of higher excited states in irradiated cyclohexane with a yield of 0.8 (100 eV) -1. These states are capable of fast energy transfer to the solute.
ISSN:0146-5724
DOI:10.1016/0146-5724(85)90201-8