Topological charge stabilization and interstellar molecules

Complete molecules detected in interstellar space were found to obey the rule of topological charge stabilization (TCS). For these interstellar molecules, the highest occupied molecular orbital (HOMO) belongs to the conjugated subsystem conforming to the TCS rule. This rule is not applicable to inco...

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Bibliographic Details
Published in:Journal of molecular structure. Theochem 1991-04, Vol.228, p.277-283
Main Author: Aihara, Jun-Ichi
Format: Article
Language:English
Subjects:
Astronomy
Atomic processes and interactions
Earth, ocean, space
Exact sciences and technology
Fundamental aspects of astrophysics
Fundamental astronomy and astrophysics. Instrumentation, techniques, and astronomical observations
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Summary:Complete molecules detected in interstellar space were found to obey the rule of topological charge stabilization (TCS). For these interstellar molecules, the highest occupied molecular orbital (HOMO) belongs to the conjugated subsystem conforming to the TCS rule. This rule is not applicable to incomplete molecules such as free radicals and ionic molecular fragments. Possible candidates for interstellar molecules are proposed.
ISSN:0166-1280
1872-7999
DOI:10.1016/0166-1280(91)90064-Q