Catalytic conversion of n-pentanol to 1,1-dialkyl ether by aluminium and iron exchanged montmorillonite catalyst

Heterogeneous catalytic conversion of n-pentanol to 1,1-dialkyl ether by Fe 3+- and Al 3+-exchanged montmorillonite catalyst was studied under different conditions. The catalyst was first heated in the presence of air or hydrogen at temperatures ranging from 80°C to 300°C and X-ray diffractometry, T...

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Bibliographic Details
Published in:Colloids and surfaces 1988, Vol.29 (4), p.337-341
Main Authors: Habib, A.M., Saafan, A.A., Abou-Seif, A.K., Salem, M.A.
Format: Article
Language:English
Subjects:
Catalysis
Catalysts: preparations and properties
Catalytic reactions
Chemistry
Exact sciences and technology
General and physical chemistry
General. Nomenclature, chemical documentation, computer chemistry
Theory of reactions, general kinetics
Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
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Summary:Heterogeneous catalytic conversion of n-pentanol to 1,1-dialkyl ether by Fe 3+- and Al 3+-exchanged montmorillonite catalyst was studied under different conditions. The catalyst was first heated in the presence of air or hydrogen at temperatures ranging from 80°C to 300°C and X-ray diffractometry, TGA, cation exchange capacity were performed. The final products were analysed by gas chromatography. It was found that Al 3+-exchanged ions are more efficient as a catalyst than the corresponding Fe 3+-exchanged ones under the same conditions.
ISSN:0166-6622
1873-4340
DOI:10.1016/0166-6622(88)80145-8