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Inferring structural changes of hydroxylic solvents from NMR data

Chemical shift data of hydroxyl nuclei can provide information on structural changes in the hydrogen bonded network of a hydroxylic solvent. This is accomplished by calculating a factor related to an apparent number of H-bonds broken, in case of temperature variations or solute additions.

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Bibliographic Details
Published in:Journal of molecular liquids 1988-03, Vol.37 (3), p.281-287
Main Authors: Mirti, Piero, Zelano, Vincenzo
Format: Article
Language:English
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Summary:Chemical shift data of hydroxyl nuclei can provide information on structural changes in the hydrogen bonded network of a hydroxylic solvent. This is accomplished by calculating a factor related to an apparent number of H-bonds broken, in case of temperature variations or solute additions.
ISSN:0167-7322
1873-3166
DOI:10.1016/0167-7322(88)80032-1