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Electron-impact-induced image contrast in FIM with organic image gases

Field-ion images of clean metal surfaces obtained by using organic image gases show bright spots rather than bright areas from surface regions of constant field strength. The origin of these spots has been investigated for cyclohexane and n-heptane as image gases and Pt/Ir tips prepared by field eva...

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Bibliographic Details
Published in:Applied surface science 1994-03, Vol.76 (1-4), p.303-306
Main Authors: Schmidt, U., Röllgen, F.W.
Format: Article
Language:English
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Summary:Field-ion images of clean metal surfaces obtained by using organic image gases show bright spots rather than bright areas from surface regions of constant field strength. The origin of these spots has been investigated for cyclohexane and n-heptane as image gases and Pt/Ir tips prepared by field evaporation. It is shown that the spots arise from field ionization (FI) of molecules on surface deposits formed by electron-impact-induced fragmentation of adsorbed image-gas molecules. The impinging electrons are provided by FI of the image-gas molecules remote from the surface even at field strengths below those required for FI of the molecules adsorbed on the metal surface.
ISSN:0169-4332
1873-5584
DOI:10.1016/0169-4332(94)90359-X