Loading…
Metal directed syntheses of metallocyclophanes containing triangular arrays of interacting redox active octahedral metal centres, x-ray crystal structure of [W(Tp ∗)(NO)(OC 6H 40)] 3
The trimeric metallocyclophanes [M(NO)(HB(3,5-Me 2,C 3,HN 2) 3(O 2C 6H 4] 4, (M = Mo, syn, syn-isomer; M = W, anti, syn-isomer) have been obtained from metal directed reactions involving the octahedral precursor complexes [M(NO)(HB(3,5-Me 2C 3HN 2) 3I 2] and 1,4-dihydroxybenzene, the structure of th...
Saved in:
Published in: | Polyhedron 1996-08, Vol.15 (21), p.3909-3913 |
---|---|
Main Authors: | , , , |
Format: | Article |
Language: | English |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
Summary: | The trimeric metallocyclophanes [M(NO)(HB(3,5-Me
2,C
3,HN
2)
3(O
2C
6H
4]
4, (M = Mo,
syn, syn-isomer; M = W,
anti, syn-isomer) have been obtained from metal directed reactions involving the octahedral precursor complexes [M(NO)(HB(3,5-Me
2C
3HN
2)
3I
2] and 1,4-dihydroxybenzene, the structure of the tungsten complex being confirmed by an X-ray diffraction study. Both compounds exhibit three well resolved reduction processes in their cycle voltammograms showing that they can exist in four distinct oxidation states. |
---|---|
ISSN: | 0277-5387 |
DOI: | 10.1016/0277-5387(96)00168-4 |