Synthesis, characterization and structure of a new μ4-S cluster [( η5-C 5H 5)Fe 3Co(CO) 11( μ4-S)]

The cluster ( η 5-C 5H 5)Fe 3Co(CO) 11( μ 4-S) was synthesized by stirring a solution of HFe 2Co(CO) 9( μ 3-S) and ( η 5-C 5H 5)Fe(CO) 2Cl in THF. It was characterized by elemental analyses, IR and 1H/ 13C NMR. The possible reaction mechanism is discussed and the structure was determined by X-ray di...

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Bibliographic Details
Published in:Polyhedron 1996-09, Vol.15 (23), p.4169-4172
Main Authors: Xu, Feng, Wen Hua Sun, Shi Yan Yang, Yuan Qi Yin, Qiang Jin Wu
Format: Article
Language:English
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Summary:The cluster ( η 5-C 5H 5)Fe 3Co(CO) 11( μ 4-S) was synthesized by stirring a solution of HFe 2Co(CO) 9( μ 3-S) and ( η 5-C 5H 5)Fe(CO) 2Cl in THF. It was characterized by elemental analyses, IR and 1H/ 13C NMR. The possible reaction mechanism is discussed and the structure was determined by X-ray diffraction.
ISSN:0277-5387
DOI:10.1016/0277-5387(96)00177-5