The dynamics of CO production from the reaction of O( 3P) with 1-and 2-butyne

The reactions of 1and 2butyne with O( 3P) were studied at 298 K by means of a CO laser resonant absorption technique. The CO formed O( 3P)+CH 3CH 2CCH→C C 3H 6 H 3CH 2CH+CO O( 3P)+CH 3CCCH 3→CH 3C C 3H 6 CH 3+CO From the kinetic modeling of the observed rates of CO formation, the rates of these...

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Published in:Chemical physics 1977-11, Vol.25 (3), p.353-359
Main Authors: Umstead, M.E., Lin, M.C.
Format: Article
Language:English
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Summary:The reactions of 1and 2butyne with O( 3P) were studied at 298 K by means of a CO laser resonant absorption technique. The CO formed O( 3P)+CH 3CH 2CCH→C C 3H 6 H 3CH 2CH+CO O( 3P)+CH 3CCCH 3→CH 3C C 3H 6 CH 3+CO From the kinetic modeling of the observed rates of CO formation, the rates of these reactions were found to be 5.0 × 10 11 and 1.6 × 10 12 ml
ISSN:0301-0104
DOI:10.1016/0301-0104(77)85145-8