Spectra of direct excitation of phosphorescence in an isotopic mixed naphthalene crystal. High resolution excitation of the two Davydov components of the N- d8 host crystal

• Published in: Chemical physics 1982-02, Vol.64 (3), p.389-398
• Main Authors: Pee, Ph, Lemaistre, J.P., Dupuy, F., Brown, R., Megel, J., Kottis, Ph
• Format: Article
• Language: English
• ISSN: 0301-0104
• DOI: 10.1016/0301-0104(82)80007-4

Direct excitation spectra of the triplet exciton band of deuterated naphthalene are presented. The high resolution spectra (0.1 cm −1) of the two Davydov components show a substructure that we attribute to the presence in the crystal of natural traps and local strains. A model based on the calculation of the eigenstates of a finite plane of molecules is provided for lineshape simulations. In this work the artificial edge effects introduced by the finite size of the model crystal are eliminated by appropriate boundary conditions. Our method allows us to introduce a random distribution of traps, with variable energies, located inside and outside the exciton band, thus featuring a real crystal. Comparison between calculations and experimental results accounts for the salient effects of the traps on the spectroscopic properties of a mixed crystal.