Gas phase high temperature photoelectron spectroscopy: The tin monoxide molecule

The HeI photoelectron spectrum of SnO (X 1Σ +) has been recorded. Two bands have been observed corresponding to ionization from the 6π and 13 ionization energies of 9.98 and 10.12 eV respectively. Vibrational structure associated with the first band has been analysed to give ▪ and D e = 3.23 ± 0.10...

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Bibliographic Details
Published in:Chemical physics 1982-06, Vol.67 (3), p.245-253
Main Authors: Dyke, J.M., Morris, A., Ridha, A.M.A., Snijders, J.G.
Format: Article
Language:English
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Summary:The HeI photoelectron spectrum of SnO (X 1Σ +) has been recorded. Two bands have been observed corresponding to ionization from the 6π and 13 ionization energies of 9.98 and 10.12 eV respectively. Vibrational structure associated with the first band has been analysed to give ▪ and D e = 3.23 ± 0.10 eV in the SnO + (X 2Π) state. An assessment has been made of the ability of Hartree-Fock-Slater calculations, multiple-scattering SCF-Xα calculations and ab ini energies for the group IV diatomic monoxide molecules.
ISSN:0301-0104
DOI:10.1016/0301-0104(82)85187-2