Optical nuclear polarization in the gas phase

Optical nuclear polarization (absorption) has been detected experimentally for the first time in benzaldehyde under UV irradiation in a magnetic field of 4.7 T. The phenomenon has been interpreted theoretically under the assumption of a non-equilibrium electron (optical) polarization transfer to the...

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Bibliographic Details
Published in:Chemical physics 1986-05, Vol.104 (3), p.415-419
Main Authors: Obynochny, A.A., Sagdeev, R.Z., Salikhov, K.M., Sukhenko, S.A., Yurkovskaya, A.V.
Format: Article
Language:English
Subjects:
Atomic and molecular physics
Exact sciences and technology
Molecular properties and interactions with photons
Nuclear resonance and relaxation
Physics
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Summary:Optical nuclear polarization (absorption) has been detected experimentally for the first time in benzaldehyde under UV irradiation in a magnetic field of 4.7 T. The phenomenon has been interpreted theoretically under the assumption of a non-equilibrium electron (optical) polarization transfer to the nuclear subsystem by a scalar cross relaxation mechanism of the second kind.
ISSN:0301-0104
DOI:10.1016/0301-0104(86)85030-3