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An NMR relaxation study on the hydrogen dynamics in malonic acid
We have studied the temperature and angular dependences of the spin—lattice relaxation time T1 in malonic acid. The results suggest that the hydrogen bonded protons of the cyclic dimers undergo fast simultaneous jumps between the two minima of asymmetric double well potential.
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Published in: | Chemical physics 1987-02, Vol.111 (3), p.439-443 |
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Main Authors: | , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | We have studied the temperature and angular dependences of the spin—lattice relaxation time T1 in malonic acid. The results suggest that the hydrogen bonded protons of the cyclic dimers undergo fast simultaneous jumps between the two minima of asymmetric double well potential. |
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ISSN: | 0301-0104 |
DOI: | 10.1016/0301-0104(87)85091-7 |