Influence of the assumed molecule environment on the value of calculated dipole moment

Dielectric measurements were conducted for five dipole liquids. Dipole moments were calculated from the experimental data using formulae divided from the Onsager theory taking into account the ellipsoidal shape of the molecule, assuming for the diluted solutions in the first case that the dipole mol...

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Bibliographic Details
Published in:Chemical physics 1988-11, Vol.127 (1), p.287-295
Main Authors: Makosz, J.J., Pełka, K.
Format: Article
Language:English
Subjects:
Atomic and molecular physics
Electric and magnetic moments (and derivatives), polarizability and magnetic susceptibility
Exact sciences and technology
Molecular properties and interactions with photons
Physics
Properties of molecules and molecular ions
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Summary:Dielectric measurements were conducted for five dipole liquids. Dipole moments were calculated from the experimental data using formulae divided from the Onsager theory taking into account the ellipsoidal shape of the molecule, assuming for the diluted solutions in the first case that the dipole molecule environment is a medium having the same permittivity as the solution and in the second case that the environment is a medium having the same permittivity as the solvent. Making use of literature data dipole moments for seventeen dipole liquids were also examined from this aspect.
ISSN:0301-0104
DOI:10.1016/0301-0104(88)87126-X