Reaction of nitrogen oxides with π-allyl complexes: A model for propylene oxidation

η 3-Allylnickel bromide dimer reacts with nitric oxide to form a 3-oxi-minopropene complex, Ni(CH 2CHCHNOH)Br(NO). μ-Dichlorobis-(η 3-allylpalladium) does not react with NO under the conditions used for the analogous nickel compound but reacts with NO 2 to give [PdCl(NO)] n and allyl nitrate. η 3-...

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Bibliographic Details
Published in:Journal of molecular catalysis 1978-01, Vol.4 (2), p.87-94
Main Authors: Clement, R.A., Klabunde, U., Parshall, G.W.
Format: Article
Language:English
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Summary:η 3-Allylnickel bromide dimer reacts with nitric oxide to form a 3-oxi-minopropene complex, Ni(CH 2CHCHNOH)Br(NO). μ-Dichlorobis-(η 3-allylpalladium) does not react with NO under the conditions used for the analogous nickel compound but reacts with NO 2 to give [PdCl(NO)] n and allyl nitrate. η 3-Allyldicarbonyl(hydrotris(pyrazolyl)borato)molybdenum(II) reacts similarly with NO 2 to give allyl nitrate and nitrosyldicarbonyl(hydrotris(pyrazolyl)borato)molybdenum, along with some 3-nitro-propene and a new nitrosylmolybdenum complex. The relevance of these results to surface processes in the heterogeneous catalysis of acrylonitrile synthesis from propylene and nitric oxide is discussed.
ISSN:0304-5102
DOI:10.1016/0304-5102(78)80001-7