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Reduction of ketones catalyzed by rhodium complexes
The hydrogenation of acetone, methyl ethyl ketone, isopropyl methyl ketone and cyclohexanone was investigated in the presence of catalysts prepared in situ in basic methanol solution from Rh 2Cl 2(C 8H 14) 4,rhodium(II) and rhodium(III) complexes and suitable ligands: 1,10-phenanthroline and 2,2...
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Published in: | Journal of molecular catalysis 1985-01, Vol.29 (1), p.13-18 |
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Main Authors: | , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | The hydrogenation of acetone, methyl ethyl ketone, isopropyl methyl ketone and cyclohexanone was investigated in the presence of catalysts prepared
in situ in basic methanol solution from Rh
2Cl
2(C
8H
14)
4,rhodium(II) and rhodium(III) complexes and suitable ligands: 1,10-phenanthroline and 2,2'-dipyridyl. The most effective catalytic system was prepared from [Rh
2Cl
2(HCOO)
2(dipy)
2]·2H
2O and 2,2'-dipyridyl in basic methanol solution. |
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ISSN: | 0304-5102 |
DOI: | 10.1016/0304-5102(85)85126-9 |