The bis(salicylaldehyde)ethylenediimine cobalt(II)-catalysed oxidative carbonylation of 1-adamantylamine in alcohol: A study for optimising carbamate formation

The oxidative carbonylation of 1-adamantylamine with dioxygen and carbon monoxide in methanol and with bis(salicylaldehyde)ethylenediimine cobalt(II) as catalyst to give the corresponding carbamate and urea is sensitive to the reaction temperature, the [substrate]/[catalyst] ratio and the pressure o...

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Bibliographic Details
Published in:Journal of molecular catalysis 1987, Vol.39 (1), p.71-77
Main Authors: Maddinelli, Giuseppe, Nali, Micaela, Rindone, Bruno, Tollari, Stefano, Cenini, Sergio, La Monica, Girolamo, Porta, Francesca
Format: Article
Language:English
Subjects:
Chemistry
Exact sciences and technology
Kinetics and mechanisms
Organic chemistry
Reactivity and mechanisms
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Summary:The oxidative carbonylation of 1-adamantylamine with dioxygen and carbon monoxide in methanol and with bis(salicylaldehyde)ethylenediimine cobalt(II) as catalyst to give the corresponding carbamate and urea is sensitive to the reaction temperature, the [substrate]/[catalyst] ratio and the pressure of the reactants. In the same conditions, diphenylmethane and anthracene exhibit only oxidation to benzophenone and anthraquinone respectively, and the antitumoral drug 3,6-diamino-2,7-dimethylacridine (acridine yellow) gives the corresponding monocarbamate.
ISSN:0304-5102
DOI:10.1016/0304-5102(87)80048-2