An efficient water-soluble ruthenium hydroformylation catalyst for the exclusive formation of 1-heptaldehyde from 1-hexene

Hydroformylation of 1-hexene was carried out in a high pressure reactor using water soluble [Ru(III)-EDTA] catalyst, synthesis gas (1:1) CO + H 2 at 50 atm, in 80:20 ethanol-water mixture and at 130 °C. The reaction proceeds with a turnover rate of 11.83 mol product per mol catalyst per hour with th...

Full description

Saved in:
Bibliographic Details
Published in:Journal of molecular catalysis 1988-11, Vol.48 (2), p.313-317
Main Authors: Khan, M.M.Taqui, Halligudi, S.B., Abdi, S.H.R.
Format: Article
Language:English
Subjects:
Catalysis
Catalysts: preparations and properties
Catalytic reactions
Chemistry
Exact sciences and technology
General and physical chemistry
General. Nomenclature, chemical documentation, computer chemistry
Theory of reactions, general kinetics
Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Hydroformylation of 1-hexene was carried out in a high pressure reactor using water soluble [Ru(III)-EDTA] catalyst, synthesis gas (1:1) CO + H 2 at 50 atm, in 80:20 ethanol-water mixture and at 130 °C. The reaction proceeds with a turnover rate of 11.83 mol product per mol catalyst per hour with the conversion of 1-hexene exclusively (100%) to linear 1-heptaldehyde.
ISSN:0304-5102
DOI:10.1016/0304-5102(88)85013-2