An efficient heterogenised palladium catalytic system for the reductive carbonylation of nitrobenzene to methyl N-phenylcarbamate

A highly active and selective heterogenised homogeneous catalyst, montmorillonitebipyridinepalladium (II) acetate complex for the reductive carbonylation of nitrobenzene to methyl N-phenylcarbamate is reported. With the additional advantages such as ease of filterability and reusability for several...

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Bibliographic Details
Published in:Journal of molecular catalysis 1994-02, Vol.88 (1), p.23-29
Main Authors: Choudary, B.M., Rao, K.Koteswara, Pirozhkov, S.D., Lapidus, A.L.
Format: Article
Language:English
Subjects:
carbonylation
Catalysis
Catalysts: preparations and properties
Chemistry
Exact sciences and technology
General and physical chemistry
methyl N-phenylcarbamate
montmorillonite
palladium
pyridine
reduction
Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
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Summary:A highly active and selective heterogenised homogeneous catalyst, montmorillonitebipyridinepalladium (II) acetate complex for the reductive carbonylation of nitrobenzene to methyl N-phenylcarbamate is reported. With the additional advantages such as ease of filterability and reusability for several cycles with consistent activity and selectivity, the heterogenised system will become practical alternative to the other systems described earlier.
ISSN:0304-5102
DOI:10.1016/0304-5102(93)E0250-K