Lifetimes of molecular negative ions of ferrocene derivatives

The lifetimes τ a of negative molecular ions of twenty ferrocene derivatives have been measured by mass spectrometry. An empirical relation was found that describes the change of τ a in this series of compounds. A model of electron ejection from the molecular ions through three channels is proposed,...

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Bibliographic Details
Published in:Journal of electron spectroscopy and related phenomena 1993-11, Vol.63 (4), p.431-438
Main Authors: Khvostenko, V.I., Asfandiarov, N.L., Lukin, V.G.
Format: Article
Language:English
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Summary:The lifetimes τ a of negative molecular ions of twenty ferrocene derivatives have been measured by mass spectrometry. An empirical relation was found that describes the change of τ a in this series of compounds. A model of electron ejection from the molecular ions through three channels is proposed, which explains the observed results.
ISSN:0368-2048
1873-2526
DOI:10.1016/0368-2048(93)80038-N