Solvent effects on the infra-red spectrum of some ruthenium nitrosyls

The nitrosyl frequencies of some ruthenium compounds of the type RuNO L 2X 3 have been studied in a variety of solvents. The NO stretching frequency varies with the solvent used; the more polar solvents raise the frequency with respect to solutions in n-hexane. For monosubstituted benzenes there is...

Full description

Saved in:
Bibliographic Details
Published in:Spectrochimica acta 1964-01, Vol.20 (11), p.1757-1761
Main Authors: Fairey, M.B., Irving, R.J.
Format: Article
Language:English
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The nitrosyl frequencies of some ruthenium compounds of the type RuNO L 2X 3 have been studied in a variety of solvents. The NO stretching frequency varies with the solvent used; the more polar solvents raise the frequency with respect to solutions in n-hexane. For monosubstituted benzenes there is a linear relationship between the dipole moment of the solvent and the increase in v NO.
ISSN:0371-1951
1873-3816
DOI:10.1016/0371-1951(64)80178-8