The far-infrared molecular dynamics of circular dichroism and optical rotatory dispersion

The nature of the far-infrared molecular dynamics of circular dichroism (CD) and optical rotatory dispersion (ORD) is investigated with field applied molecular dynamics simulation (FMD) in chiral (S)-CHBrCIF and achiral water ensembles. Rosenfeld tensor symmetries show that femtosecond transients an...

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Bibliographic Details
Published in:Physics letters. A 1992-12, Vol.171 (5), p.355-359
Main Authors: Evans, M.W., Woźniak, S., Wagnière, G.
Format: Article
Language:English
Subjects:
Atomic and molecular physics
Exact sciences and technology
Molecular properties and interactions with photons
Optical activity and dichroism
magnetooptical and electrooptical spectra
Physics
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Summary:The nature of the far-infrared molecular dynamics of circular dichroism (CD) and optical rotatory dispersion (ORD) is investigated with field applied molecular dynamics simulation (FMD) in chiral (S)-CHBrCIF and achiral water ensembles. Rosenfeld tensor symmetries show that femtosecond transients and steady state correlation functions are different in the chiral ensemble but identical in the achiral ensemble for right and left circularly polarised components of a laser.
ISSN:0375-9601
1873-2429
DOI:10.1016/0375-9601(92)90657-8