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Possible peculiarities of the infrared absorption spectra of molecules adsorbed on rough surfaces

Possible peculiarities of the enhanced infrared absorption spectra of molecules adsorbed on rough surfaces are considered. It is pointed out that for symmetrical molecules the band determined by the breathing mode must be most enhanced. Besides, the bands determined by the vibrations, transforming a...

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Bibliographic Details
Published in:Physics letters. A 1993-12, Vol.183 (5), p.403-407
Main Author: Polubotko, A.M.
Format: Article
Language:English
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Summary:Possible peculiarities of the enhanced infrared absorption spectra of molecules adsorbed on rough surfaces are considered. It is pointed out that for symmetrical molecules the band determined by the breathing mode must be most enhanced. Besides, the bands determined by the vibrations, transforming according to the unitary irreducible representation, and by the representation which describes the transformational properties of the moment d z , will be enhanced also.
ISSN:0375-9601
1873-2429
DOI:10.1016/0375-9601(93)90596-R