Solubility of pure 1,3 butadiene and methyl propene and their mixtures in pure n-methyl-2-pyrrolidone and in its aqueous solutions

The solubility of pure 1,3 butadiene and methyl propene and their mixtures in pure n-methyl-2-pyrrolidone and in its aqueous solutions was measured at several temperatures and pressures. For this purpose, experimental methodologies were established in order to evaluate thermodynamic equilibrium vari...

Full description

Saved in:
Bibliographic Details
Published in:Fluid phase equilibria 1996-04, Vol.118 (1), p.133-141
Main Authors: Vladimir de Oliveira, J., Cohen Uller, A.M.
Format: Article
Language:English
Subjects:
Chemistry
Data
Exact sciences and technology
Experiments
General and physical chemistry
Solubility
Solubility of gas in liquid
Solutions
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The solubility of pure 1,3 butadiene and methyl propene and their mixtures in pure n-methyl-2-pyrrolidone and in its aqueous solutions was measured at several temperatures and pressures. For this purpose, experimental methodologies were established in order to evaluate thermodynamic equilibrium variables. A simple weighing method was used to obtain the experimental data. From the experimental results, the parameters of conventional excess Gibbs free energy models, Wilson, NRTL and UNIQUAC, were determined through the Maximum Likelihood method.
ISSN:0378-3812
1879-0224
DOI:10.1016/0378-3812(95)02847-1