Organic-inorganic salts made by TTF and magnetic clusters

We present a first report of the new organic-inorganic salts formed by the organic donor TTF and the inorganic clusters [Co4(H2O)2(PW9O34)2]−10 and [Cr(OH)6Mo6O18]−3. We show that these metal oxide anions can be used successfully as magnetic components of radical ion salts based on TTF-type radicals...

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Bibliographic Details
Published in:Synthetic metals 1993-03, Vol.56 (1), p.2023-2027
Main Authors: Gomez-Garcia, C.J., Borras-Almenar, J.J., Coronado, E., Delhaes, P., Garrigou-Lagrange, C., Baker, L.C.W.
Format: Article
Language:English
Subjects:
Condensed matter: electronic structure, electrical, magnetic, and optical properties
Exact sciences and technology
high spin clusters
ion-radical salts
magnetic materials
Magnetic properties and materials
Physics
polyoxometalates
Studies of specific magnetic materials
TTF
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Summary:We present a first report of the new organic-inorganic salts formed by the organic donor TTF and the inorganic clusters [Co4(H2O)2(PW9O34)2]−10 and [Cr(OH)6Mo6O18]−3. We show that these metal oxide anions can be used successfully as magnetic components of radical ion salts based on TTF-type radicals. On the other hand, the magnetic features of these salts provide some evidence of the presence of substantial interactions between the two components.
ISSN:0379-6779
1879-3290
DOI:10.1016/0379-6779(93)90366-5