Vibrational spectra and assignments in di- t-butyl peroxide

The infra-red spectrum of di- t-butyl peroxide has been obtained in the gas, liquid and solid states between 1500 and 400cm −1*. The Raman spectrum of the liquid has also been re-investigated and qualitative polarization data obtained. The two sets of t-butoxy frequencies appear to combine to give m...

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Bibliographic Details
Published in:Spectrochimica acta. Part A: Molecular spectroscopy 1967-01, Vol.23 (3), p.605-609
Main Authors: McKean, D.C., Duncan, J.L., Hay, R.K.M.
Format: Article
Language:English
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Summary:The infra-red spectrum of di- t-butyl peroxide has been obtained in the gas, liquid and solid states between 1500 and 400cm −1*. The Raman spectrum of the liquid has also been re-investigated and qualitative polarization data obtained. The two sets of t-butoxy frequencies appear to combine to give modes of A− species intense in the Raman effect and motions of A− ” species strongly active in the infra-red. OO stretching motion is associated with the pair of Raman frequencies 904 and 862cm −1.
ISSN:0584-8539
DOI:10.1016/0584-8539(67)80317-9