Vibrational spectra of some tetrahalo-complexes of cobalt(II), nickel(II) and manganese(II)

Raman and infra-red studies of complexes of the type MX 4 2−, where M = Co, Ni and Mn and X = Cl, Br and I, are presented and bond-stretching force constants are calculated. A previous report of apparent force-constant anomaly in the case of MnBr 4 2− is shown to have been erroneous.

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Bibliographic Details
Published in:Spectrochimica acta. Part A: Molecular spectroscopy 1970-01, Vol.26 (2), p.287-290
Main Authors: Edwards, H.G.M., Woodward, L.A., Gall, M.J., Ware, M.J.
Format: Article
Language:English
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Summary:Raman and infra-red studies of complexes of the type MX 4 2−, where M = Co, Ni and Mn and X = Cl, Br and I, are presented and bond-stretching force constants are calculated. A previous report of apparent force-constant anomaly in the case of MnBr 4 2− is shown to have been erroneous.
ISSN:0584-8539
DOI:10.1016/0584-8539(70)80072-1