Laser Raman spectrum of the dichloroiodinium (ICl 2+) cation

The solid addition compounds ICl 3.SbCl 5 and ICl 3.AlCl 3were prepared and their Raman spectra studied. The results are interpreted on the basis of an ionic structure containing the ICl 2 + cation, which is a bent ion with C 2 v symmetry. The Raman frequencies are: v 1 = 366, v 2 = 149 and v 3 = 37...

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Bibliographic Details
Published in:Spectrochimica acta. Part A: Molecular spectroscopy 1973-01, Vol.29 (6), p.873-878
Main Authors: Shamir, J., Rafaeloff, R.
Format: Article
Language:English
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Summary:The solid addition compounds ICl 3.SbCl 5 and ICl 3.AlCl 3were prepared and their Raman spectra studied. The results are interpreted on the basis of an ionic structure containing the ICl 2 + cation, which is a bent ion with C 2 v symmetry. The Raman frequencies are: v 1 = 366, v 2 = 149 and v 3 = 372 cm −1.
ISSN:0584-8539
DOI:10.1016/0584-8539(73)80129-1