Spectra and structure of phosphorus-boron compounds—XVI. Vibrational studies of P-octamethylcyclotetraboraphosphane

The i.r. spectra of P-octamethylcyclotetraboraphosphane was examined in the solid phase (3500-30 cm −1) and in the gaseous phase (3500-200 cm −1). The Raman spectra of this compound (3500-10cm −1) were recorded in the solid and liquid phases. The vibrational spectra are consistent with D 2d symmetry...

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Bibliographic Details
Published in:Spectrochimica acta. Part A: Molecular spectroscopy 1977, Vol.33 (9), p.893-899
Main Authors: Durig, J.R., Sens, M.A., Kalasinsky, V.F., Odom, J.D.
Format: Article
Language:English
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Summary:The i.r. spectra of P-octamethylcyclotetraboraphosphane was examined in the solid phase (3500-30 cm −1) and in the gaseous phase (3500-200 cm −1). The Raman spectra of this compound (3500-10cm −1) were recorded in the solid and liquid phases. The vibrational spectra are consistent with D 2d symmetry in all phases. There appears to be minimal factor group effects in the solid phase. The results are discussed in relation to recent NMR work and vibrational work with the closely related six-membered boron phosphorus rings.
ISSN:0584-8539
DOI:10.1016/0584-8539(77)80088-3