Copper(I) and silver(I) complexes of 2-amino-5-methyl-1,3,4-thiadiazole and 2,5-dimethyl-1,3,4-thiadiazole

The copper(I) and silver(I) complexes of 2-amino-5-methyl-1,3,4- thiadiazole (MATZ = L) CuL 3X (X = Cl, ClO 4), CuL 1.5 Br, CuLI, AgLX (X = ClO 4, CF 3COO, 1 2 SO 4), AgL 2.5X (X = BF 4, NO 3) and 2,5-dimethyl-1,3,4-thiadiazole (DTZ = L′) CuL′ 0.5X (X = Cl, I), CuL′Br, AgL′X (X = ClO 4, CF 3COO), Ag...

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Bibliographic Details
Published in:Spectrochimica acta. Part A: Molecular spectroscopy 1980, Vol.36 (7), p.689-691
Main Authors: Fabretti, A.C., Franchini, G.C., Peyronel, G.
Format: Article
Language:English
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Summary:The copper(I) and silver(I) complexes of 2-amino-5-methyl-1,3,4- thiadiazole (MATZ = L) CuL 3X (X = Cl, ClO 4), CuL 1.5 Br, CuLI, AgLX (X = ClO 4, CF 3COO, 1 2 SO 4), AgL 2.5X (X = BF 4, NO 3) and 2,5-dimethyl-1,3,4-thiadiazole (DTZ = L′) CuL′ 0.5X (X = Cl, I), CuL′Br, AgL′X (X = ClO 4, CF 3COO), AgL′ 0.5 X (X = NO 3, BF 4(H 2O)) have been prepared and studied by conductometric and i.r. methods. MATZ is coordinated through the aminic nitrogen atom and in some complexes also through one or two ring-nitrogen atoms. DTZ is coordinated to the copper(I) atom only through the ring-nitrogen atom, while in its silver(I) complexes also the ring-sulphur atom seems to participate in the coordination.
ISSN:0584-8539
DOI:10.1016/0584-8539(80)80029-8