Comparison of the FT Raman spectra of inorganic tetrahedral ions over the temperature range 77 to 473 K

The vibrational spectra recorded over a wide temperature range (77–473 K) of a number of inorganic transition metal salts containing tetraoxyanions in both solution and crystal phases are reported. All modes in these cases are Raman active and the bands predicted by site-symmetry analysis are observ...

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Bibliographic Details
Published in:Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy Molecular and biomolecular spectroscopy, 1995-11, Vol.51 (12), p.2027-2037
Main Authors: Pope, Simon J.A, West, Yvonne D
Format: Article
Language:English
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Summary:The vibrational spectra recorded over a wide temperature range (77–473 K) of a number of inorganic transition metal salts containing tetraoxyanions in both solution and crystal phases are reported. All modes in these cases are Raman active and the bands predicted by site-symmetry analysis are observed. Only bands assigned as ν 3 and ν 1 are found to be temperature dependent. The significance of this is discussed.
ISSN:1386-1425
DOI:10.1016/0584-8539(95)01509-1