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A helium inductively coupled plasma for atomic emission spectrometry

An annular helium inductively coupled plasma (He ICP) was generated at atmospheric pressure. No external cooling was used to stabilize the plasma. Aqueous solution was injected into the plasma without any difficulty. Preliminary results revealed that the annular He ICP was capable of exciting elemen...

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Bibliographic Details
Published in:Spectrochimica acta. Part B: Atomic spectroscopy 1985, Vol.40 (10), p.1467-1472
Main Authors: Chan, Shi-Kit, Montaser, Akbar
Format: Article
Language:English
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Summary:An annular helium inductively coupled plasma (He ICP) was generated at atmospheric pressure. No external cooling was used to stabilize the plasma. Aqueous solution was injected into the plasma without any difficulty. Preliminary results revealed that the annular He ICP was capable of exciting elements such as Cl and Br which possess high excitation energies. Atomic emission detection limits for Cl and Br were improved by factors of 63 and 34, respectively, as compared to the results obtained from the argon inductively coupled plasma. The excitation temperature of the annular He ICP (4180 K) was less than that of an Ar ICP (5570 K).
ISSN:0584-8547
1873-3565
DOI:10.1016/0584-8547(85)80170-1