Polymers containing metal chelate units. IV. Immobilised complexes of transition metal acrylates with 2,2′-dipyridyl and 1,10-phenanthroline

Several metal chelate monomers have been synthesized by the interaction of nickel(II), cobalt(II) and chromium(III) acrylates with 2,2′-dipyridyl or 1,10-phenanthroline in alcohol. Their composition, spectral (UV, visible, near IR, and IR) and magnetic properties have been investigated. A method of...

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Bibliographic Details
Published in:Reactive polymers 1989, Vol.11 (3), p.221-226
Main Authors: Uflyand, I.E., Kokoreva, I.V., Starikov, A.G., Sheinker, V.N., Pomogailo, A.D.
Format: Article
Language:English
Subjects:
Applied sciences
Exact sciences and technology
Physicochemistry of polymers
Polymerization
Polymers and radiations
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Summary:Several metal chelate monomers have been synthesized by the interaction of nickel(II), cobalt(II) and chromium(III) acrylates with 2,2′-dipyridyl or 1,10-phenanthroline in alcohol. Their composition, spectral (UV, visible, near IR, and IR) and magnetic properties have been investigated. A method of immobilising metal chelate monomers on a polytetrafluoroethylene surface by suspension grafting polymerization has been developed. A comparative analysis of physico-chemical properties of the low molecular weight complexes and their immobilised analogues has been conducted.
ISSN:0923-1137
1873-1678
DOI:10.1016/0923-1137(89)90107-3