Functionalization and hybridization of poly(vinyl chloride) III. Transformation of poly(vinyl chloride) into water-crosslinkable polymer

A trimethoxysilyl group, which reacts easily with water, was introduced into poly(vinyl chloride) (PVC) in homogeneous and heterogeneous reactions. The polymers obtained were crosslinked in the presence of water, and crosslinking was accelerated in the presence of acid or base.

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Bibliographic Details
Published in:Reactive polymers 1994, Vol.22 (2), p.139-143
Main Authors: Yamamoto, Tamotsu, Inada, Hitoshi, Isozaki, Shigeru, Okawara, Makoto
Format: Article
Language:English
Subjects:
3-(Trimethoxysilyl)propanethiol
3-(Trimethoxysilyl)propyl propyl sulfide
Applied sciences
Chemical modifications
Chemical reactions and properties
Exact sciences and technology
Organic polymers
Physicochemistry of polymers
Poly(vinyl chloride)
Silane coupling group
Water-crosslinkable polymer
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Description
Summary:A trimethoxysilyl group, which reacts easily with water, was introduced into poly(vinyl chloride) (PVC) in homogeneous and heterogeneous reactions. The polymers obtained were crosslinked in the presence of water, and crosslinking was accelerated in the presence of acid or base.
ISSN:0923-1137
1873-1678
DOI:10.1016/0923-1137(94)90145-7