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Applied correlated crystal field
Attempts are made to fit the lines of rare earth optical spectra with scaled point charge electrostatic parameters associated with one-electron operators and polarized point dipole parameters associated with two-electron operators. The test materials are Pr 3+- and Nd 3+-doped Y 2O 3 and Nd 2O 3. In...
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Published in: | Journal of alloys and compounds 1993-03, Vol.193 (1), p.210-212 |
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Main Authors: | , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | Attempts are made to fit the lines of rare earth optical spectra with scaled point charge electrostatic parameters associated with one-electron operators and polarized point dipole parameters associated with two-electron operators. The test materials are Pr
3+- and Nd
3+-doped Y
2O
3 and Nd
2O
3. In addition, the radial variation law of the one-particle crystal field parameters with the rare earth-ligand distance is re-examined with reference to experimental data and two-electron hybrid integral values. |
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ISSN: | 0925-8388 1873-4669 |
DOI: | 10.1016/0925-8388(93)90351-M |