The crystal structure of some rhenium and technetium dichalcogenides

• Published in: Journal of alloys and compounds 1996-08, Vol.241 (1), p.34-39
• Main Authors: Lamfers, H.-J., Meetsma, A., Wiegers, G.A., de Boer, J.L.
• Format: Article
• Language: English
• Subjects: Cluster; Group VII 4d and 5d transition metal dichaleogenides; Layer structure; Metal metal bond
• ISSN: 0925-8388; 1873-4669
• DOI: 10.1016/0925-8388(96)02313-4

The crystal structures of ReSe., ReS., ReSSe and TeS 2 are determined using single crystal X-ray diffraction. The compounds are triclinic with space group Pl. ReSe., ReS, and ReSSe have a distorted CdCl 2-type structure: TeS 2 has a distorted Cd(OH)-type structure. In the case of ReS, there are two sandwiches in the unit cell, related by symmetry centers. The other compounds have one sandwich per unit cell and the centers of symmetry are within the Re (Tc)-layer. In all compounds the Re (Te) atoms in each layer form parallelogram-shaped connected clusters with Re Re (Te Te) distances of ca. 2.7–2.8Å, in the cluster and ca. 2.9Å, between clusters. The chains of clusters run along the a-axis. Unit cell dimensions and structure of ReS, differ from the one reported recently by Murray et al. Inorg. Chem., 33 (1994) 4418) where only one sandwich is present and the centers of symmetry are in the Re layer. The structure of ReSe 2 differs from that reported by Alcock and Kjekshus ( Acta Chem. Scand., 19 (1965) 79), in the sense that these authors interchanged inversion-centers and pseudo-centers.