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Catalytic activity of nickel sulfide catalysts supported on Al-pillared montmorillonite for thiophene hydrodesulfurization

Al-pillared clays, prepared by exchange with partly hydrolyzed aluminium nitrate solutions, dried in air or freeze-dried, and calcined, were used as supports for nickel sulfide catalysts. The catalysts were tested on their hydrodesulfurization (HDS) activity for thiophene. The catalysts show a high...

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Bibliographic Details
Published in:Applied catalysis. A, General General, 1993-04, Vol.97 (1), p.77-85
Main Authors: Kloprogge, J.T., Welters, W.J.J., Booy, E., de Beer, V.H.J., van Santen, R.A., Geus, J.W., Jansen, J.B.H.
Format: Article
Language:English
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Summary:Al-pillared clays, prepared by exchange with partly hydrolyzed aluminium nitrate solutions, dried in air or freeze-dried, and calcined, were used as supports for nickel sulfide catalysts. The catalysts were tested on their hydrodesulfurization (HDS) activity for thiophene. The catalysts show a high thiophene HDS activity. It appears that details in the preparation and calcination of the pillared clays have a strong influence on the catalytic activity.
ISSN:0926-860X
1873-3875
DOI:10.1016/0926-860X(93)80068-2