6-Amino-1,11-dimethyl-6,7-dihydro-5H-dibenzo[a,c]cycloheptene-6-carboxylic acid: The first chiral α-amino acid without asymmetric carbon atom

The title compound 4, possessing a biaryl axis as the sole source of chirality, has been prepared in the enantiomerically pure ( R) as well as racemic form by two alternative procedures starting from dibromide 1. Graphic

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Bibliographic Details
Published in:Tetrahedron: asymmetry 1996, Vol.7 (1), p.231-236
Main Authors: Ridvan, Luděk, Abdallah, Nevine, Holakovský, Roman, Tichý, Miloš, Závada, Jiří
Format: Article
Language:English
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Summary:The title compound 4, possessing a biaryl axis as the sole source of chirality, has been prepared in the enantiomerically pure ( R) as well as racemic form by two alternative procedures starting from dibromide 1. Graphic
ISSN:0957-4166
1362-511X
DOI:10.1016/0957-4166(95)00440-8