Multicomponent sequential injection analysis determination of nitro-phenols in waters by on-line liquid-liquid extraction and preconcentration

• Published in: Analytica chimica acta 2000-09, Vol.421 (2), p.155-166
• Main Authors: Cladera, Andreu, Miró, Manuel, Estela, José Manuel, Cerdà, Vı́ctor
• Format: Article
• Language: English
• Subjects: Analysis methods; Analytical chemistry; Applied sciences; Chemistry; Exact sciences and technology; Extraction; Multicomponent analysis; Natural water pollution; Nitrophenols; Pollution; Sequential injection; Spectrometric and optical methods; Water treatment and pollution
• ISSN: 0003-2670; 1873-4324
• DOI: 10.1016/S0003-2670(00)01035-7

An automatic sequential injection analysis (SIA) set-up for the determination of phenolic compounds (2-, 3- and 4-nitrophenol) in waters was designed and evaluated. The system performs an on-line phenol extraction from an aqueous medium to an organic solvent, which enables the analyte isolation and preconcentration. The extracted phenols are on-line back-extracted into a small volume of NaOH solution and conducted to a spectrophotometric detector for quantitative analysis. This methodology is based on the formation of a thin organic solvent layer adhered to the PTFE surface of the extraction coil. In the present work, no reversed-flow was carried out in both the extraction and back-extraction steps. By using a photodiode-array detector, multilinear regression algorithms and first derivative spectroscopic techniques were evaluated in order to perform multicomponent determinations of phenol mixtures. Concentrations within the range 0.4–4.6 mg l −1 of 2-nitrophenol, 0.6–11.2 mg l −1 of 3-nitrophenol and 55.6–938 mg l −1 of 4-nitrophenol have been determined and simultaneously analysed at a frequency of four samples per hour. A R.S.D. of 2.2% was obtained for 2.6 mg l −1 of 2-nitrophenol, 2.3% for 5.3 mg l −1 of 3-nitrophenol and 2.2% for 330.8 μg l −1 of 4-nitrophenol, with preconcentration factors comprised between seven and nine.