Hydrolysis of some methylphosphonites and methylphosphinates

The hydrolysis of some methylphosphonites and methylphosphinates was studied in the pH range 4.5–7.5 by phosphorus-31 nuclear magnetic resonance spectrometry. For methylphosphonites, a two-step reaction mechanism was observed in which formation of the corresponding methylphosphinates was followed by...

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Bibliographic Details
Published in:Analytica chimica acta 1983, Vol.151, p.221-225
Main Authors: Verweij, A., Dekker, W.H., Beck, H.C., Boter, H.L.
Format: Article
Language:English
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Summary:The hydrolysis of some methylphosphonites and methylphosphinates was studied in the pH range 4.5–7.5 by phosphorus-31 nuclear magnetic resonance spectrometry. For methylphosphonites, a two-step reaction mechanism was observed in which formation of the corresponding methylphosphinates was followed by production of methylphosphinic acid. Implications of the results obtained on the applicability of a verification procedure for nerve gases in surface waters are discussed.
ISSN:0003-2670
1873-4324
DOI:10.1016/S0003-2670(00)80079-3