Chemiluminescence of bis(2,4,6-trichlorophenyl) oxalate in aqueous micellar systems

The chemiluminescent reaction of bis(2,4,6-trichlorophenyl) oxalate (TCPO) in aqueous micellar systems is compared with the reaction in a mixture of acetonitrile and aqueous phosphate buffer. The chemiluminescence was studied in batch experiments with perylene as the fluorophore. The oxidation of TC...

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Bibliographic Details
Published in:Analytica chimica acta 1989, Vol.217 (2), p.229-237
Main Authors: Steijger, O.M., van Mastbergen, H.M., Holthuis, J.J.M.
Format: Article
Language:English
Subjects:
Analytical chemistry
Chemistry
Exact sciences and technology
Spectrometric and optical methods
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Summary:The chemiluminescent reaction of bis(2,4,6-trichlorophenyl) oxalate (TCPO) in aqueous micellar systems is compared with the reaction in a mixture of acetonitrile and aqueous phosphate buffer. The chemiluminescence was studied in batch experiments with perylene as the fluorophore. The oxidation of TCPO produced the same intensity of chemiluminescence in the buffered acetonitrile as in Arkopal N-300 micelles, the best micellar system. The solubility of TCPO in an aqueous micellar system is greater than that in the acetonitrile/aqueous buffer (80:20, v/v), but TCPO is less stable in the former system.
ISSN:0003-2670
1873-4324
DOI:10.1016/S0003-2670(00)80405-5