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Analysis of traces of polycyclic aromatic hydrocarbons by adsorption on cobalt phthalocyanine and barium salts of sulphophthalocyanines followed by thermal desorption gas chromatograph

Small amounts of polycyclic aromatic hydrocarbons (PAHs) in aqueous solution were almost completely adsorbed on barium salts of copper (II) sulphophthalocyanines and cobalt (II) phthalocyanine, which were precipitated from the solution. Recoveries of the PAHs from the precipitates by thermal desorpt...

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Bibliographic Details
Published in:Analytica chimica acta 1989, Vol.224, p.1-11
Main Authors: Kusuda, Kousuke, Shiraki, Kaneto, Miwa, Toshio
Format: Article
Language:English
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Summary:Small amounts of polycyclic aromatic hydrocarbons (PAHs) in aqueous solution were almost completely adsorbed on barium salts of copper (II) sulphophthalocyanines and cobalt (II) phthalocyanine, which were precipitated from the solution. Recoveries of the PAHs from the precipitates by thermal desorption gas chromatography were 71–95%. The method is useful for the concentration and analysis of medium molecular weight, thermally stable PAHs.
ISSN:0003-2670
1873-4324
DOI:10.1016/S0003-2670(00)83438-8