Potentiometric titration of palladium(II) halide complex anions based on ion-pair formation

Palladium(II) halide complex anions can be titrated with different quaternary salt solutions. Titrations can be monitored potentiometrically with a simple PVC membrane-coated aluminium wire electrode. A comparative study with different cationic titrants showed the dependence of the titration stoichi...

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Bibliographic Details
Published in:Analytica chimica acta 1988, Vol.209, p.357-361
Main Authors: Vytřas, K., Kalous, J., Šimíčková, B., Černá, J., Šílená, I.
Format: Article
Language:English
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Summary:Palladium(II) halide complex anions can be titrated with different quaternary salt solutions. Titrations can be monitored potentiometrically with a simple PVC membrane-coated aluminium wire electrode. A comparative study with different cationic titrants showed the dependence of the titration stoichiometry on the structure of the cationic reagent used. The procedures can be utilized for monitoring the Pd(II) concentration in galvanic contact baths.
ISSN:0003-2670
1873-4324
DOI:10.1016/S0003-2670(00)84586-9