Nuclear overhauser effect and conformational states of cellobiose in aqueous solution

A nuclear Overhauser enhancement in α-cellobiose 1-phosphate, resulting from pre-irradiation of H-1′ of the non-reducing glucosyl group, was measured and calculated theoretically. Comparison of these data reveals a complicated conformational equilibrium in aqueous solutions of the cellobiose derivat...

Full description

Saved in:
Bibliographic Details
Published in:Carbohydrate research 1985-09, Vol.141 (2), p.191-197
Main Authors: Lipkind, Grigory M., Shashkov, Alexander S., Kochetkov, Nikolay K.
Format: Article
Language:English
Subjects:
Atomic and molecular physics
Barrier heights (internal rotation, inversion, rotational isomerism, conformational dynamics)
Exact sciences and technology
Molecular properties and interactions with photons
Physics
Properties of molecules and molecular ions
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:A nuclear Overhauser enhancement in α-cellobiose 1-phosphate, resulting from pre-irradiation of H-1′ of the non-reducing glucosyl group, was measured and calculated theoretically. Comparison of these data reveals a complicated conformational equilibrium in aqueous solutions of the cellobiose derivative.
ISSN:0008-6215
1873-426X
DOI:10.1016/S0008-6215(00)90451-8