Nuclear overhauser effects for methyl β-maltoside and the conformational states of maltose in aqueous solution

A nuclear Overhauser enhancement in methyl β-maltoside, resulting from pre-irradiation of H-1′ of the non-reducing glucose residue, has been measured and calculated theoretically. Comparison of these data reveals a complicated conformational equilibrium in aqueous solutions of maltose derivatives....

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Bibliographic Details
Published in:Carbohydrate research 1986-03, Vol.147 (2), p.175-182
Main Authors: Shashkov, Alexander S., Lipkind, Grigory M., Kochetkov, Nikolay K.
Format: Article
Language:English
Subjects:
Atomic and molecular physics
Exact sciences and technology
General molecular conformation and symmetry
stereochemistry
Molecular properties and interactions with photons
Physics
Properties of molecules and molecular ions
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Summary:A nuclear Overhauser enhancement in methyl β-maltoside, resulting from pre-irradiation of H-1′ of the non-reducing glucose residue, has been measured and calculated theoretically. Comparison of these data reveals a complicated conformational equilibrium in aqueous solutions of maltose derivatives.
ISSN:0008-6215
1873-426X
DOI:10.1016/S0008-6215(00)90628-1