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Intercalation of sodium with its halides into graphite

Ternary GICs containing sodium associated with chloride, bromide and iodide ions have been synthesized by heating graphite with liquid sodium in the presence of NaCl, NaBr, and NaI in solid or liquid state. Similar ternary compounds could not be obtained with NaF, but quaternary phases G–Na–I–F and...

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Bibliographic Details
Published in:Carbon (New York) 2000, Vol.38 (14), p.1955-1963
Main Authors: Hérold, Abert, Marêché, Jean-François, Lelaurain, Michèle
Format: Article
Language:English
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Summary:Ternary GICs containing sodium associated with chloride, bromide and iodide ions have been synthesized by heating graphite with liquid sodium in the presence of NaCl, NaBr, and NaI in solid or liquid state. Similar ternary compounds could not be obtained with NaF, but quaternary phases G–Na–I–F and G–Na–Cl–F have been synthesized.
ISSN:0008-6223
1873-3891
DOI:10.1016/S0008-6223(00)00039-7