Properties of graphite prepared from boron-doped pitch as an anode for a rechargeable Li ion battery

• Published in: Carbon (New York) 2002-01, Vol.40 (4), p.567-574
• Main Authors: Fujimoto, Hiroyuki, Mabuchi, Akihiro, Natarajan, Chinnasamy, Kasuh, Takahiro
• Format: Article
• Language: English
• Subjects: A. Doped carbons; Applied sciences; B. Graphitization; C. X-ray diffraction; D. Electrochemical properties; Direct energy conversion and energy accumulation; Electrical engineering. Electrical power engineering; Electrical power engineering; Electrochemical conversion: primary and secondary batteries, fuel cells; Exact sciences and technology
• ISSN: 0008-6223; 1873-3891
• DOI: 10.1016/S0008-6223(01)00152-X

Boron-doped graphites were derived from a naphthalene-based pitch mixed with para-xylene glycol (PXG) or dimethyl para-xylene glycol (DMPXG) as a cross-linking agent and three types of boron-containing compounds as a graphitization catalyst, and their anode performances were investigated. The structural analysis of the obtained graphites revealed that PXG functioned mainly as a two-dimensional cross-linking agent during the heat treatment process and DMPXG functioned partially as a three-dimensional. The average interlayer spacing decreased and lattice constant, a 0, and graphitizability increased with increasing the amount of boron atoms added. The result indicated that the carbon atoms were replaced by boron atoms. The anode performance was improved by the enhancement of graphitizability. The structural parameters and anode performance of boron-doped graphites did not depend on the kind of boron-containing compounds but the amount of boron atoms added in pitch and the kind of cross-linking agent.